AI-তৈরি নমুনা উত্তর
Molar mass of K2Cr2O7=(2×39.1)+(2×52)+(7×16)=294.2 g/mol
Concentration of K2Cr2O7 solution,
S1=M×V (in L)w=294.2×0.2501.47111≈0.02 M
The balanced redox reactions are:
- Cr2O72−+6I−+14H+→2Cr3++3I2+7H2O
- 2S2O32−+I2→S4O62−+2I−
From the stoichiometric ratio:
1 mol K2Cr2O7≡3 mol I2≡6 mol Na2S2O3
Applying the equivalence relation:
nNa2S2O3=6×nK2Cr2O7
V2×S2=6×V1×S1
Given, V1=20 mL, V2=20 mL:
20×S2=6×20×0.02
S2=6×0.02=0.12 M
Therefore, the concentration of the Na2S2O3 solution is 0.12 M.