AI-লিখিত অনুমানভিত্তিক উত্তর—ধারণা ও সীমাবদ্ধতা নিচে উল্লেখ করা হয়েছে। এটি উৎসের যাচাইকৃত মূল উত্তর হিসেবে দাবি করা হচ্ছে না।
স্পষ্ট অনুমান: Standard values for specific heat and latent heat in SI units are used: s_ice = 2100 J/(kg·K), L_f = 3.36 × 10^5 J/kg, s_water = 4200 J/(kg·K), L_v = 2.26 × 10^6 J/kg. | The notation 'θ\theta°C' is evaluated both as an arbitrary sub-zero/zero initial temperature θ°C and as a likely typo for 0°C.
Let the initial temperature of ice be θ∘C=(273+θ) K, where θ≤0.
Mass of ice, m=1 kg.
Standard thermodynamic constants:
- Specific heat capacity of ice, sice=2100 J/(kg⋅K)
- Specific latent heat of fusion of ice, Lf=3.36×105 J/kg
- Specific heat capacity of water, swater=4200 J/(kg⋅K)
- Specific latent heat of vaporization of water, Lv=2.26×106 J/kg
The conversion takes place in up to four stages:
-
Heating ice from θ∘C to 0∘C:
ΔS1=∫273+θ273TmsicedT=msiceln(273+θ273)=2100ln(273+θ273) J/K
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Melting ice at 0∘C (273 K) into water at 0∘C:
ΔS2=TfmLf=2731×3.36×105≈1230.77 J/K
-
Heating water from 0∘C (273 K) to 100∘C (373 K):
ΔS3=mswaterln(273373)=1×4200×ln(273373)≈4200×0.31212≈1310.89 J/K
-
Vaporizing water at 100∘C (373 K) into steam at 100∘C:
ΔS4=TbmLv=3731×2.26×106≈6058.98 J/K
Total change in entropy:
ΔS=ΔS1+ΔS2+ΔS3+ΔS4
ΔS=2100ln(273+θ273)+1230.77+1310.89+6058.98
ΔS=2100ln(273+θ273)+8600.64 J/K
Special Case (if initial temperature was 0∘C, i.e., θ=0):
ΔS1=0
ΔS=1230.77+1310.89+6058.98≈8600.64 J/K≈8.60×103 J/K