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7.

The entropy change to convert 1 kg of ice at θ\theta°C to steam at 100°C is to be determined.

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স্পষ্ট অনুমান: Standard values for specific heat and latent heat in SI units are used: s_ice = 2100 J/(kg·K), L_f = 3.36 × 10^5 J/kg, s_water = 4200 J/(kg·K), L_v = 2.26 × 10^6 J/kg. | The notation 'θ\theta°C' is evaluated both as an arbitrary sub-zero/zero initial temperature θ°C and as a likely typo for 0°C.

Let the initial temperature of ice be θ∘C=(273+θ) K\theta^\circ\text{C} = (273 + \theta)\text{ K}, where θ≤0\theta \le 0.
Mass of ice, m=1 kgm = 1\text{ kg}.

Standard thermodynamic constants:

  • Specific heat capacity of ice, sice=2100 J/(kg⋅K)s_{\text{ice}} = 2100\text{ J}/(\text{kg}\cdot\text{K})
  • Specific latent heat of fusion of ice, Lf=3.36×105 J/kgL_f = 3.36 \times 10^5\text{ J}/\text{kg}
  • Specific heat capacity of water, swater=4200 J/(kg⋅K)s_{\text{water}} = 4200\text{ J}/(\text{kg}\cdot\text{K})
  • Specific latent heat of vaporization of water, Lv=2.26×106 J/kgL_v = 2.26 \times 10^6\text{ J}/\text{kg}

The conversion takes place in up to four stages:

  1. Heating ice from θ∘C\theta^\circ\text{C} to 0∘C0^\circ\text{C}:
    ΔS1=∫273+θ273msiceT dT=msiceln⁡(273273+θ)=2100ln⁡(273273+θ) J/K\Delta S_1 = \int_{273+\theta}^{273} \frac{m s_{\text{ice}}}{T}\,dT = m s_{\text{ice}} \ln\left(\frac{273}{273 + \theta}\right) = 2100 \ln\left(\frac{273}{273 + \theta}\right)\text{ J/K}

  2. Melting ice at 0∘C0^\circ\text{C} (273 K273\text{ K}) into water at 0∘C0^\circ\text{C}:
    ΔS2=mLfTf=1×3.36×105273≈1230.77 J/K\Delta S_2 = \frac{m L_f}{T_f} = \frac{1 \times 3.36 \times 10^5}{273} \approx 1230.77\text{ J/K}

  3. Heating water from 0∘C0^\circ\text{C} (273 K273\text{ K}) to 100∘C100^\circ\text{C} (373 K373\text{ K}):
    ΔS3=mswaterln⁡(373273)=1×4200×ln⁡(373273)≈4200×0.31212≈1310.89 J/K\Delta S_3 = m s_{\text{water}} \ln\left(\frac{373}{273}\right) = 1 \times 4200 \times \ln\left(\frac{373}{273}\right) \approx 4200 \times 0.31212 \approx 1310.89\text{ J/K}

  4. Vaporizing water at 100∘C100^\circ\text{C} (373 K373\text{ K}) into steam at 100∘C100^\circ\text{C}:
    ΔS4=mLvTb=1×2.26×106373≈6058.98 J/K\Delta S_4 = \frac{m L_v}{T_b} = \frac{1 \times 2.26 \times 10^6}{373} \approx 6058.98\text{ J/K}

Total change in entropy:
ΔS=ΔS1+ΔS2+ΔS3+ΔS4\Delta S = \Delta S_1 + \Delta S_2 + \Delta S_3 + \Delta S_4
ΔS=2100ln⁡(273273+θ)+1230.77+1310.89+6058.98\Delta S = 2100 \ln\left(\frac{273}{273 + \theta}\right) + 1230.77 + 1310.89 + 6058.98
ΔS=2100ln⁡(273273+θ)+8600.64 J/K\Delta S = 2100 \ln\left(\frac{273}{273 + \theta}\right) + 8600.64\text{ J/K}

Special Case (if initial temperature was 0∘C0^\circ\text{C}, i.e., θ=0\theta = 0):
ΔS1=0\Delta S_1 = 0
ΔS=1230.77+1310.89+6058.98≈8600.64 J/K≈8.60×103 J/K\Delta S = 1230.77 + 1310.89 + 6058.98 \approx 8600.64\text{ J/K} \approx 8.60 \times 10^3\text{ J/K}

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